基于电化学法的铬盐清洁生产工艺研究          下载免费PDF全文

冯海涛  董亚萍  梁建  李波  张波  李武  郑竹林 《盐湖研究》2019,27(4):9-17

现有铬盐生产技术阻碍了铬盐行业的清洁化发展,研发新型铬盐生产技术实属必要。中国科学院青海盐湖研究所自行研发出一套以电化学法为基础的铬盐清洁生产工艺,涵盖三条大工艺和四种母系铬盐产品。包括氢氧化钠溶液中电化学氧化铬铁制备铬酸钠联产三氧化二铬和三氧化二铁工艺,离子膜电解法从铬酸钠合成重铬酸钠工艺,以及离子膜电解法从重铬酸钠合成铬酸酐工艺。相比现有铬盐生产技术,该技术的优势主要体现在以下五点:温和化、去渣化、高值化、自动化和高效化。目前相关研发工作业已走出实验室,走过产业化中间试验,正向产业化示范线迈进。  相似文献   

Spatiotemporal heterogeneity and influencing mechanism of ecosystem services in the Pearl River Delta from the perspective of LUCC     

Zhou  Rubo  Lin  Meizhen  Gong  Jianzhou  Wu  Zhuo 《地理学报(英文版)》2019,29(5):831-845

Journal of Geographical Sciences - Land use/land cover change (LUCC) has considerable impact on ecosystem services. It is essential to quantify the spatiotemporal heterogeneity of ecosystem...  相似文献   

Water mining from the deep critical zone by apple trees growing on loess     

Huijie Li  Bingcheng Si  Pute Wu  Jeffrey J. McDonnell 《水文研究》2019,33(2):320-327

There have been significant recent advances in understanding the ecohydrology of deep soil. However, the links between root development and water usage in the deep critical zone remains poorly understood. To clarify the interaction between water use and root development in deep soil, we investigated soil water and root profiles beyond maximum rooting depth in five apple orchards planted on farmland with stand ages of 8, 11, 15, 18, and 22 years in a subhumid region on the Chinese Loess Plateau. Apple trees rooted progressively deeper for water with increasing stand age and reached 23.2 ± 0.8 m for the 22‐year‐old trees. Soil water deficit in deep soil increased with tree age and was 1,530 ± 43 mm for a stand age of 22 years. Measured root deepening rate was far great than the reported pore water velocity, which demonstrated that trees are mining resident old water. The deficits are not replenished during the life‐span of the orchard, showing a one‐way mining of the critical zone water. The one‐way root water mining may have changed the fine root profile from an exponential pattern in the 8‐year‐old orchard to a relative uniform distribution in older orchards. Our findings enhance our understanding of water‐root interaction in deep soil and reveal the unintended consequences of critical zone dewatering during the lifespan of apple trees.  相似文献   

Spatial and temporal variability of stable isotopes (δ18O and δ2H) in surface waters of arid,mountainous Central Asia     

Huawu Wu  Jinglu Wu  Kadyrbek Sakiev  Jinzhao Liu  Jing Li  Bin He  Ya Liu  Beibei Shen 《水文研究》2019,33(12):1658-1669

Characterization of spatial and temporal variability of stable isotopes (δ¹⁸O and δ²H) of surface waters is essential to interpret hydrological processes and establish modern isotope–elevation gradients across mountainous terrains. Here, we present stable isotope data for river waters across Kyrgyzstan. River water isotopes exhibit substantial spatial heterogeneity among different watersheds in Kyrgyzstan. Higher river water isotope values were found mainly in the Issyk‐Kul Lake watershed, whereas waters in the Son‐Kul Lake watershed display lower values. Results show a close δ¹⁸O–δ²H relation between river water and the local meteoric water line, implying that river water experiences little evaporative enrichment. River water from the high‐elevation regions (e.g., Naryn and Son‐Kul Lake watershed) had the most negative isotope values, implying that river water is dominated by snowmelt. Higher deuterium excess (average d = 13.9‰) in river water probably represents the isotopic signature of combined contributions from direct precipitation and glacier melt in stream discharge across Kyrgyzstan. A significant relationship between river water δ¹⁸O and elevation was observed with a vertical lapse rate of 0.13‰/100 m. These findings provide crucial information about hydrological processes across Kyrgyzstan and contribute to a better understanding of the paleoclimate/elevation reconstruction of this region.  相似文献   

The vertical influence of temperature and precipitation on snow cover variability in the Central Tianshan Mountains,Northwest China     

Senyao Wu  Xueliang Zhang  Jinkang Du  Xiaobing Zhou  Ye Tuo  Runjie Li  Zheng Duan 《水文研究》2019,33(12):1686-1697

Seasonal snow cover in mountainous regions will affect local climate and hydrology. In this study, we assessed the role of altitude in determining the relative importance of temperature and precipitation in snow cover variability in the Central Tianshan Mountains. The results show that: (a) in the study area, temperature has a greater influence on snow cover than precipitation during most of the time period studied and in most altitudes. (b) In the high elevation area, there is a threshold altitude of 3,900 ± 400 m, below which temperature is negatively correlated whereas precipitation is positively correlated to snow cover, and above which the situation is the opposite. Besides, this threshold altitude decreases from snow accumulated period to snow stable period and then increases from snowmelt period to snow‐free period. (c) Below 2,000 m, there is another threshold altitude of 1,400 ± 100 m during the snow stable period, below (above) which precipitation (temperature) is the main driver of snow cover.  相似文献   

Modelling the time‐dependent behaviour of granular material with hypoplasticity          下载免费PDF全文

Shun Wang  Wei Wu  Zhen‐Yu Yin  Chong Peng  Xuzhen He 《国际地质力学数值与分析法杂志》2018,42(12):1331-1345

This paper presents a constitutive model for time‐dependent behaviour of granular material. The model consists of 2 parts representing the inviscid and viscous behaviour of granular materials. The inviscid part is a rate‐independent hypoplastic constitutive model. The viscous part is represented by a rheological model, which contains a high‐order term denoting the strain acceleration. The proposed model is validated by simulating some element tests on granular soils. Our model is able to model not only the non‐isotach behaviour but also the 3 creep stages, namely, primary, secondary, and tertiary creep, in a unified way.  相似文献   

Exploring the interaction of surface roughness and slope gradient in controlling rates of soil loss from sloping farmland on the Loess Plateau of China     

Taotao Li  Longshan Zhao  Hongteng Duan  Yifan Yang  Yu Wang  Faqi Wu 《水文研究》2020,34(2):339-354

Surface roughness and slope gradient are two important factors influencing soil erosion. The objective of this study was to investigate the interaction of surface roughness and slope gradient in controlling soil loss from sloping farmland due to water erosion on the Loess Plateau, China. Following the surface features of sloping farmland in the plateau region, we manually prepared rough surfaces using four tillage practices (contour drilling, artificial digging, manual hoeing, and contour plowing), with a smooth surface as the control measure. Five slope gradients (3°, 5°, 10°, 15°, and 20°) and two rainfall intensities (60 and 90 mm/hr) were considered in the artificial rainfall simulation experiment. The results showed that the runoff volume and sediment yield increased with increasing slope gradient under the same tillage treatment. At gentle slope gradients (e.g., 3° and 5°), the increase in surface roughness prevented the runoff and sediment production, that is, the surface roughness reduced the positive effect of slope gradient on the runoff volume and sediment yield to a certain extent. At steep slope gradients, however, the enhancing effect of slope gradient on soil erosion gradually increased and surpassed the reduction effect of surface roughness. This study reveals the existence of a critical slope gradient that influences the interaction of surface roughness and slope gradient in controlling soil erosion on sloping farmland. If the slope gradient is equal to or less than the critical value, an increase in surface roughness would decrease soil erosion. Otherwise, the increase in surface roughness would be ineffective for preventing soil erosion. The critical slope gradient would be smaller under higher rainfall intensity. These findings are helpful for us to understand the process of soil erosion and relevant for supporting soil and water conservation in the Loess Plateau region of China.  相似文献   

An experimental approach for determination of the Weibull homogeneity index of rock or rock-like materials     

Pan  Xiaohua  Guo  Wei  Wu  Shifan  Chu  Jian 《Acta Geotechnica》2020,15(2):375-391

Acta Geotechnica - The spatial variation of the physical–mechanical properties of rock or rock-like materials is an intrinsic characteristic of the materials induced by multiscale material...  相似文献   

A method for aligning the plastic scintillator detector on DAMPE     

Peng-Xiong Ma  Yong-Jie Zhang  Ya-Peng Zhang  Yao Li  Jing-Jing Zang  Xiang Li  Tie-Kuang Dong  Yi-Zhong Fan  Shi-Jun Lei  Jian Wu  Yu-Hong Yu  Qiang Yuan  Chuan Yue  Zhi-Yu Sun 《天文和天体物理学研究(英文版)》2019,(6)

The Plastic Scintillator Detector(PSD) onboard the DArk Matter Particle Explorer(DAMPE)is designed to measure cosmic ray charge(Z) and to act as a veto detector for gamma ray identification.To fully exploit the charge identification potential of PSD and to enhance its capability to identify gamma ray events, we develop an alignment method for the PSD. The path length of a given track in the volume of a PSD bar is derived taking into account the shift and rotation alignment corrections. By examining energy spectra of corner-passing events and fully contained events, position shifts and rotations of all PSD bars are obtained, and are found to be on average about 1 mm and 0.0015 radian respectively. To validate the alignment method, we introduce artificial shifts and rotations of PSD bars into the detector simulation.These shift and rotation parameters can be recovered successfully by the alignment procedure. As a result of the PSD alignment procedure, the charge resolution of the PSD is improved from 4% to 8%, depending on the nuclei.  相似文献   

Mapping 3D visibility in an urban street environment from mobile LiDAR point clouds     

Yi Zhao  Jianping Wu  Song Shu  Handong Liang  Min Liu 《地理信息系统科学与遥感》2020,57(6):797-812

ABSTRACT

Visibility determination is a key requirement in a wide range of national and urban applications, such as national security, landscape management, and urban design. Mobile LiDAR point clouds can depict the urban built environment with a high level of details and accuracy. However, few three-dimensional visibility approaches have been developed for the street-level point-cloud data. Accordingly, an approach based on mobile LiDAR point clouds has been developed to map the three-dimensional visibility at the street level. The method consists of five steps: voxelization of point-cloud data, construction of lines-of-sight, construction of sectors of sight, construction of three-dimensional visible space, and calculation of volume index. The proposed approach is able to automatically measure the volume of visible space and openness at any viewpoint along a street. This approach has been applied to three study areas. The results indicated that the proposed approach enables accurate simulation of visible space as well as high-resolution (1 m × 1 m) mapping of the visible volume index. The proposed approach can make a contribution to the improvement of urban planning and design processes that aim at developing more sustainable built environments.  相似文献